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Re: [ccp4bb] Vapor diffusion calculator

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CCP4bb <-- 1999 <-- November 1999 <-- 30 November 1999
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From: Ian Tickle I {- dot -} Tickle {- at -} ASTEX-THERAPEUTICS {- dot -} COM
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Subject: Re: Vapor diffusion calculator
From: Clemens Grimm Clemens {- dot -} Grimm {- at -} BIOZENTRUM {- dot -} UNI-WUERZBURG {- dot -} DE
Date: 2010-02-03

Zitat von Imre Toeroe :

> Hi,
>
> this might be relevant here:
>
> http://scripts.iucr.org/cgi-bin/paper?S0907444995000436
>

Yes! thanks for the link.

> Imre
>
> Clemens Grimm wrote:
>> regardless of what such a (kinetic) calculator will calculate at the end -
>> we will have to feed it with data of the type "vapour pressure vs.
>> concentration and temperature" of substance X. Even without a whole
>> simulation tool for the kinetics of a vapour diffusion experiment
>> this will already enable us to tell what the equilibrium
>> state/endpoint of the experiment will be.
>> As the substances we are interested in are typically stuff like
>> PEGs and at very high concentration (non-ideal behaviour!), we will
>> need experimental data. For some salts there are tables. But for
>> PEGs etc. this has to be generated. I feel that only having this
>> kind of data at hand would already be tremendously useful!
>>
>> Clemens
>>
>>
>> Zitat von Jacob Keller :
>>
>> Dear Crystallographers,
>>
>> Is anybody aware of a calculator for vapor diffusion experiments to
>> plot concentrations of various solvent components as a function of
>> time? For a simple example, what happens when I mix a protein
>> solution containing 50mM NaCl 1:1 with a reservoir containing 50%
>> MPD but no salt? Where is the vapor diffusion equilibrium, and how
>> does the drop composition change as a function of time? More
>> complicated would be experiments involving volatile components
>> other than water, as I think, for example, ethanol would almost
>> instantly equilibrate, then the water diffusion would kick in over
>> a longer time scale. Even more complicated would be pH-dependent
>> volatilities such as acetate. I don't think this would be
>> impossible to figure out, but it would be nice if there were a
>> pre-existing tool/server to do such.
>>
>> Regards,
>>
>> Jacob Keller
>>
>>
>> *******************************************
>> Jacob Pearson Keller
>> Northwestern University
>> Medical Scientist Training Program
>> Dallos Laboratory
>> F. Searle 1-240
>> 2240 Campus Drive
>> Evanston IL 60208
>> lab: 847.491.2438
>> cel: 773.608.9185
>> email: j-keller2@northwestern.edu
>> *******************************************
>>
>>
>> --------------------------------------------------
>> Dr. Clemens Grimm
>> Institut für Biochemie
>> Biozentrum der Universität Würzburg
>> Am Hubland
>> D-97074 Würzburg
>> Germany
>> e-mail: Clemens.Grimm@biozentrum.uni-wuerzburg.de
>> phone : +49 0931 888 84031
>> -------------------------------------------------
>
>



--------------------------------------------------
Dr. Clemens Grimm
Institut für Biochemie
Biozentrum der Universität Würzburg
Am Hubland
D-97074 Würzburg
Germany
e-mail: Clemens.Grimm@biozentrum.uni-wuerzburg.de
phone : +49 0931 888 84031
-------------------------------------------------




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